The following initial rate data was collected for the reaction, A + 2B ⟶ \longrightarrow ⟶
B. Find the rate constant
The following initial rate data was collected for the reaction, 2 NO + O2 _2 2 ⟶ \longrightarrow ⟶ 2 _2 2
[NO2 _2 2 X ^X X 2 _2 2 Y ^Y Y
For the mechanism below, determine the overall rate law.
2 N O + B r 2 ⟶ 2 N O B r o v e r a l l 2~NO~+~Br_2~\longrightarrow~2~NOBr~~{overall} 2 NO + B r 2 ⟶ 2 NOB r o v er a ll
N O + B r 2 ⇋ k − 1 k 1 N O B r 2 NO+~Br_2~\mathop{\leftrightharpoons}^{k_1}_{k_{-1}}~NOBr_2 NO + B r 2 ⇋ k − 1 k 1 NOB r 2
N O B r 2 + N O → k 2 2 N O B r NOBr_2~+~NO~\xrightarrow{k_2}~2NOBr NOB r 2 + NO k 2 2 NOB r
Derive the rate law given the elementary steps.
C l 2 ⇋ k − 1 k 1 2 C l 1 Cl_2~\mathop{\leftrightharpoons}^{k_1}_{k_{-1}}~2~Cl~~{1} C l 2 ⇋ k − 1 k 1 2 Cl 1
C l + C H C l 3 → k 2 H C l + C C l 3 2 Cl+~CHCl_3~\xrightarrow{k_2}~HCl~+~CCl_3~~{2} Cl + C H C l 3 k 2 H Cl + CC l 3 2
C l + C C l 3 → k 3 C C l 4 3 Cl~+~CCl_3~\xrightarrow{k_3}~CCl_4~~{3} Cl + CC l 3 k 3 CC l 4 3
