General Chemistry 2: Rates of Reaction

For the proposed mechanism below, identify the intermediates and determine the rate law.

$2~NO_2~+~F_2~\leftrightharpoons~2~NO_2F~~{overall}$

$NO_2F_2+~Br_2~\longrightarrow~NO_2F~+~F~~{slow step}$

$NO_2~+~F~\longrightarrow~NO_2F$

For the proposed mechanism below, find the overall reaction, identify the intermediates, then determine the rate law.

$CL_2~\leftrightharpoons~2~Cl$

$2~Cl~+2~NO~\longrightarrow~2~NOCl$

Find the rate law for the following reaction mechanism using the pseudo(quasi) steady state hypothesis

$A + B~\longrightarrow~C$

$C~\longrightarrow~D$

Derive the rate law for the following reaction mechanism

$OCl^-~H_2O~\leftrightharpoons~HOCl + OH^-$

$I^- + HOCl~\longrightarrow~HOI + Cl^-~~{slow step}$

$HO + OH^-\longrightarrow~H_2O + OI^-$